Such clays act like sponges in their capacity to soak up water. Actually, the clays form by addition of water and weathering of "primary" silicates, commonly found as volcanic rocks on the surface of Mars.
Opportunity's results mirror data from Martian rocks at Gale crater obtained by Curiosity rover earlier this year. But they contradict the vast majority of previous mineral analyses, which showed most hydrated rocks were formed of sulphates. Those minerals, such as gypsum, formed in dilute sulphuric acid. Instead, the chemistry reported this week from Esperance implies that the clays formed there had formed in waters that would have been drinkable.
"This is powerful evidence that water interacted with this rock to change its chemistry and mineralogy in a dramatic way," Steve Squyres of Cornell University, science team leader of the Opportunity mission, told the New York Times.
It is the strongest evidence yet for a past Martian environment that would have been conducive to life.
Speculation linking the origins of life on Earth to the presence of clay minerals has been something of a theme since first suggested in the early 1950s. Swelling clays, like those seen at Esperance, demonstrate the presence of neutral water early in Mars' history. But at the molecular scale the inter-layer structure of the clay can also act as a template to any organic molecules present and, potentially, promote replication of enzymes and proteins, which are necessary for life.
The findings back up earlier theories that the Martian surface once hosted an ocean, covering much of its Northern Hemisphere.
After the landing of Curiosity rover in 2012 with its much upgraded sets of analysis tools, Opportunity's work acts as independent verification of some of Curiosity's findings. Opportunity launched on July 7, 2003 and was designed to operate on Mars only for 90 days after landing. But it has far exceeded expectations, even when its twin rover, Spirit, ground to a halt back in 2010.
As its 10th anniversary nears and the rover trundles on its explorations by moving to new rocks, these new results demonstrate the ageing rover's value and make it worthy of celebration.
Simon Redfern is Professor of Mineral Physics at University of Cambridge.
theconversation.edu.au