Deadly clashes broke out between police and nationalist protesters in Kiev after Ukrainian politicians gave their support for greater autonomy in the separatist regions in the east.
At least two officers were killed and more than 140 people injured after grenades and firearms were used in some of the worst violence in the capital since the revolution that overthrew Viktor Yanukovych in February last year.
Igor Derbin, 25, was shot in the heart and Dmitry Slastikov died from injuries after a grenade explosion, the Interior Ministry said.
Both riot police and protesters used batons, tear gas and smoke bombs before a live hand grenade was thrown into a crowd outside the parliament building.