"We've got some HAZMAT crews en route aswell because there will be a fuel spill associated with the boat," Fire and Rescue NSW Superintendent Luke Unsworth told NCA NewsWire just after 6pm.
The boat exploded at Dangar Island on the Hawkesbury. Photo / 7News
"This is quite a significant event, having (this number of) people with significant burns is a significant event."
It took firefighters almost an hour to put out the blaze and crews remained at the scene at 7pm to help contain any chemicals.