"China is one of New Zealand's most important relationships. Signing this agreement today builds on the significant benefits both countries have enjoyed as a result of our existing FTA."
For the first time, environmental considerations have been included in the upgrade - meaning both countries have committed to ensuring environmental standards aren't lowered for a trade or investment advantage or used for trade protectionist purposes.
It will also ensure that most of New Zealand's $3 billion wood and paper trade to China will be tariff-free.
The considerations are "the most ambitious trade and environment chapter and the highest level of commitment that China has agreed in any FTA", O'Connor said.
The upgrade will make exporting to China easier and cheaper by, for example, simplifying documentation requirements and establishing dedicated contacts for New Zealand businesses at key ports in China.
In addition, all safeguard tariffs in dairy are set to be eliminated within one year for most products, and three years for milk powder.
"This means that by 1 January 2024, all New Zealand dairy exports to China will be tariff free," O'Connor said.
"Protections in the existing agreement that are important to New Zealanders, such as our rules on overseas investment and the Treaty of Waitangi exception, remain in place."
He said benefits would be seen across a range of exporting sectors including seafood, the forestry sector, and other primary sector industries, as well as those in services, including advertising, education, and aviation-related services.
The renewed agreement would deepen "our relationship further" and give exporters the "best possible access to the China market", he said.
However, before the agreement is enforced it will be have to be approved by Parliament first.
China is New Zealand's largest trading partner, with two-way goods and services trade now exceeding $32b a year.