It was followed by Cheviot in North Canterbury (37C), and Clyde in Central Otago which reached its hottest temperature on record (36.7).
Earlier in the day, at 1pm, Hanmer Forest and Waiau in Canterbury were hottest at 35.6C.
Meanwhile MetService also recorded some South Island centres in the high thirties.
Alexandra in Central Otago was the warmest in the country at 36.4C.
While in the North Island, Masterton was the hottest at 34.8C, MetService meteorologist April Clark said.
However, the South Island would soon see some reprieve.
As of Thursday places like Alexandra were expected to drop 20C over the next 72 hours.
"Alexandra is on 36C at the moment, then it could drop to 21C on Thursday then to 16C on Friday."
A "true southerly" with cool air from the Southern oceans was expected to chill the Otago and Canterbury regions as a low moved to meet a soon-to-be ex-tropical cyclone.
It would likely bring heavy rain and winds.
"They can expect some cooler temperatures, as well as rain, a lot of people will be pleased about that," Clark said.
Heavy rain was expected on the west coast of the South Island from late Wednesday night.
The North Island should not expect the wind and rain until Friday.