Ben Donaldson will instead don the Wallabies’ No 10 jersey for their do-or-die match against Wales on Monday morning (NZT).
Gordon was Jones’ only specialist first five in Australia’s World Cup squad and his departure to the bench left Donaldson - a surprise selection at fullback in Australia’s opening two matches - to fill the void at 10 for what is a must-win for the Wallabies to avoid an embarrassing pool-play exit from the World Cup.
Andrew Kellaway has been called into the team to wear the No 15 jersey against the Welsh.
Veteran halfback Nic White has also been moved back to the bench to make way for Tate McDermott, who has passed fitness tests after missing the Fiji match due to concussion.
In another twist to the seemingly never-ending captaincy changes in the Wallabies, David Porecki - who led the team against the Fijians - has retained the captaincy despite McDermott being the squad’s official vice-captain. Injured skipper Will Skelton is still not fit.
Jones said: “Every team has matches like this during a Rugby World Cup and for this young team it is this week.
“We’ve prepared well, are focused on what we need to do, and we’ll be ready to fight.”