Williams will play just his seventh game of the rugby season and second test for the All Blacks this year following a string of injuries and illness.
The 33-year-old was set to come off the bench two weeks ago against South Africa but was ruled out following tonsillitis.
He's managed just 442 minutes on the field this season. He broke a wrist in Cape Town while touring with the Blues and had minor knee surgery which ruled him out of the first two tests against France.
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And then, when he got his chance against the French in Dunedin in late June, he injured a shoulder which has ruled him out until recently.
Williams will start alongside Ryan Crotty in the midfield.
"Just grateful to be back playing in the squad. Just been a food bill the last few weeks I've been around but I just haven't been able to get back out there or get the body right. Just excited to get back out there," Williams said today.
Williams said he still has nerves heading into Sunday's test in Buenos Aires as the All Blacks face a confident Pumas side coming off wins against the Springboks and Australia.
"For me of course you feel nerves. It's a little bit daunting going out in the spotlight again. But I try and thrive in that. I try and walk towards it and get excited about it and just understand the beast we're going up against.
"They've come off a couple of really big wins, a great tour and they're back home and ready to go. Understanding that but also understanding that I'm excited myself and look forward to that challenge."
All Blacks team to play Argentina at Estadio Jose Amalfitani on Sunday at 11.40am, is:
15. Ben Smith
14. Waisake Naholo
13. Ryan Crotty
12. Sonny Bill Williams
11. Rieko Ioane
10. Beauden Barrett
9. TJ Perenara
8. Luke Whitelock
7. Sam Cane
6. Shannon Frizell
5. Scott Barrett
4. Sam Whitelock ©
3. Ofa Tuungafasi
2. Codie Taylor
1. Karl Tu'inukuafe
Reserves: Nathan Harris, Tim Perry, Angus Ta'avao, Patrick Tuipulotu, Ardie Savea, Aaron Smith, Richie Mo'unga, Anton Lienert-Brown.