Known as "Brys'' to her loved ones, the young mum had been on her way to Paeroa to enjoy a few drinks with a group of friends.
She planned to leave her car there and stay the night. The family found out an hour later she had been involved in a devastating accident.
Debbie said her daughter, a donor, had a very rare blood type, AB negative, and so the decision was made to donate Brylee's organs.
Her voice breaking, Debbie said she was happy that her daughter's special gift would help save up to three lives.
'Charlie was the light of her life'
AB negative is the rarest of all eight blood groups, shared by only 1 per cent of New Zealanders.
One donor can transform the lives of up to 10 people waiting for transplants of hearts, lungs, livers, kidneys, pancreas, eye tissue, heart valves and skin.
Family members are now rallying to support and raise Charlie.
"She was a great mum to Charlie. He was just the light of her life," Debbie said.
The family did not know the circumstances that led to the crash - whether Brylee may have been going too fast, was reaching out to get something she had dropped, or simply grabbed her phone for some reason.
Debbie said texting and driving was something her daughter was very much against, but "you never know".
The Serious Crash Unit is investigating the circumstances of the crash.
The national road toll up to 10.50am yesterdaywas 255, down from 277 and 280 at the same times in the past two years. However 64 people have died so far this year in the Waikato, up from 54 at this time last year and the highest death toll for in the region at least five years.