She said there were multiple risks involved - including the structural integrity of fire-damaged buildings, weapons available to the inmates involved, and the toxicity of burnt building materials.
Burns also pinpointed the violence "being offered" by the prisoners.
Specialist Corrections staff are involved in the situation, in a bid to negotiate with those involved still.
Corrections said anyone who surrendered would immediately be given food and water, as well as support.
"As prisoners surrender, they will be secured, searched, provided with food and water, assessed by medical staff and will have access to kaumātua and other support."
Burns said they had a duty of care to the men involved.
"It is likely that they will remain in our custody for a number of years to come."
A police spokeswoman said this morning officers remained on the ground helping staff from Corrections, which is the leading agency for anything to do with the incident.
In the past few days, information has trickled out of the prison about the reasons behind the riot.
Sources have said the men were making a stand against conditions they had experienced at the prison facility over the past year.
"Our water comes out brown," one inmate told Radio NZ.
"But we still have to drink it. We sit and eat in the same room we sleep in.
"We get [a] towel and clothes changes once a week - clothes that don't even fit."
Last night, Corrections said: "They have had multiple regular opportunities to comply with staff."