The union was still going on with pay equity claims for other early childhood educators, who make up the vast majority of the sector, she said.
Kindergarten teachers have been voting in an online ballot, after four days of negotiations between the union and the ministry.
The new collective agreement will see entry level trained teachers' pay go from $48,410 to $51,358 while the most senior staff will receive up to $107,770.
The ministry's deputy secretary for early learning, Ellen MacGregor-Reid, welcomed the agreement.
What the deal includes:
• Pay parity with primary and secondary school teachers, including the same pay increases and unified pay scale.
• An increase to head teacher and senior teacher pay.
• A one-off payment of $1500 for NZEI members.
• A commitment to Te Tiriti o Waitangi.