Over dinner later Ms Collins had the opportunity to chat with Jolie and her fiance Brad Pitt with whom she had a "nice little chat".
"I initially said to him 'you wouldn't be interested in coming and doing a movie here would you?'
The Hollywood A-lister told her he was keen to do a motorcycle tour of New Zealand. "I, of course, alerted the Minister of Tourism - John Key. He thought it was a great idea too."
Ms Collins tweeted pictures of herself with the couple, the first time she has used the social media network after a self-imposed ban a month ago after she used it to wrongly accuse Press Gallery reporter Katie Bradford of seeking her intervention in a personal matter.
While in the UK Ms Collins has also met a series of ministers including Home Secretary Theresa May, Attorney-General Dominic Grieve, and Minister of Justice Chris Grayling.
The agenda for talks has included issues around crime prevention, particularly around domestic and sexual violence and "Clare's Law" or the Domestic Violence Disclosure Scheme put in place in Britain after the murder of Clare Wood by her former boyfriend in 2009.