Environment Southland staff say they are "concerned" as flood water threatens an old paper mill storing chemicals which could turn toxic when mixed with water.
Thousands of tonnes of a potentially dangerous chemical — known as ouvea premix — are still stored in the former Carter Holt Harvey paper mill in Mataura.
The dross from the New Zealand Aluminium Smelters' (NZAS) Tiwai Point smelter is classified as a class 6 hazardous substance, which can generate poisonous ammonia gas if it comes into contact with water.
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Emergency Management Southland said emergency services and others have carried out further flood protection works by sandbagging around the building.