"There's a fairly high chance of cloud in the north and west of both islands. It's not everywhere but at this stage it's looking fairly cloudy. The east areas shouldn't be too bad."
Christchurch residents would have a good chance of seeing the supermoon, as well as those in Hawke's Bay.
Wellingtonians and Aucklanders may catch a glimpse of it. "It's not an exact moment, so you've basically just got to stay up and hope for a break in the clouds."
MetService meteorologist Lisa Murray also expected East Coasters to catch the best views, particularly those in the South Island.
"There's rain moving in for much of the North Island and the West Coast which is expected to linger."
Auckland's Stardome Observatory astronomer Grant Christie said the best time to see the supermoon was as it rose after sunset.
"It's only when the moon's near the horizon that you get any appreciation of its size. Once it's high up in the sky, you don't really notice any particular difference."
The phenomenon occurs when a full moon coincides with its closest approach to Earth.
As its orbit around Earth is an ellipse, not a circle, the moon's distance from Earth can vary from a distant apogee of 406,000km to a closer perigee of 357,000km, although these ranges can also vary because the orbit of the moon is affected by the sun's gravity.
The moon passes through apogee and perigee each lunar cycle, and the phases of the moon and the orbit aren't directly linked, so occasionally a full moon will coincide with perigee, resulting in a supermoon.
The moon will actually be closest to the Earth - just 356,509km away - at 12.23am on Tuesday.
The exact time of the full moon occurs a little after this at 2.52am, at which time the moon will appear high in the sky and noticeably brighter.