Foreign Minister Murray McCully has added his voice to international calls for restraint and for the Security Council to take the lead to prevent any further escalation of tensions between Russia and Ukraine.
Mr McCully said developments in Ukraine over the weekend were "deeply worrying" after reports Russian military were mobilising in Crimea, which is part of Ukraine but where Russia has a naval base.
Russia's President Vladimir Putin has also secured Parliament's signoff to invade Ukraine, claiming it could be necessary to protect the interests of Russian citizens. That has prompted Ukraine to put its Armed Forces on high alert and increase security at military and nuclear bases.
President Barack Obama called on President Putin to withdraw its forces in a phone call.