"It is like putting a curtain around the hemisphere, which reflects the sunlight, and cools the air [below the ash]."
Dr Salinger said the cooling effect would be barely noticeable - the tens of thousands of tonnes of sulphur units could lead to a cooling of 0.2C over two months.
The Pinatubo eruption in the Philippines in 1991 spewed one million sulphur units into the air, leading to a 2C to 3C drop over three years.
The Chilean ash cloud reached New Zealand because it was thrown 15km into the air, where it piggy-backed on fast-moving trade winds - which are the same height as jet aircraft cruising levels.
It is being propelled by two different jet streams over New Zealand, which are travelling between 30m and 60m a second.
University of Auckland volcanologist Jan Lindsay said the vast size of the plumes was the result of its highly volatile source.
"Eruptions of rhyolite magma [in Chile] are among the most explosive on earth, because the magma's high silica content makes it hard for gases to escape passively.
"Instead they tend to blast the magma apart into billions of tiny fragments, generating huge, high ash columns."
Those vast columns have forced contrasting responses from trans-tasman airlines.
Jetstar and Qantas said it was "not worth the risk" to fly, but Air New Zealand has not cancelled any flights.
Aviation commentator Peter Clark said the differing decisions depended on airlines' safety policies, but were probably also influenced by cost.
Flying an aircraft below about 6000m uses around 10 per cent more fuel because of greater air resistance.
Mr Clark said Air New Zealand would have easily recouped this cost through passengers from cancelled flights who changed carriers.
He also suggested that Jetstar and Qantas may have been reluctant to send too many planes to New Zealand during an Australian national holiday for fears they would become trapped in overseas airports by heavier ash.
Volcanic ash acts like coarse sandpaper on an aircraft's exterior, but can also clog engines.
But because it was launched into the stratosphere (roughly 6100m upwards), Air New Zealand faced little risk in flying its planes below it.
When the ash dropped into the troposphere, it was broken up by normal weather patterns.
Ash cloud details
Distance travelled: 9,000km
Speed over NZ: 30-60 metres/second
Height above NZ: 8.5km - 10km
Depth: at least 2km
Potential effect on climate: -0.2C
Concentration of SO2: 10,000s of tonnes
Size of volcanic particles: 50 microns (2 hair widths)