But she found her feet in the dating game after meeting Kopua in a Hamilton nightclub just a few months later.
The couple have already bought a house in Hamilton and Kopua supported Williams during major surgery after she injured her ankle at last year's World Netball Championships.
The couple flew to Fiji for a week after Christmas and announced their engagement on Facebook when returning home last week.
"Fiji was beautiful, sunshine-locked and a huge surprise, we got engaged. yay," Williams wrote.
Congratulations flooded in this week from fellow Silver Ferns stars including Irene van Dyk, Cathrine Latu and former captain Adine Wilson.
Wilson, married to former All Black Jeff Wilson, said: "Congrats, wedding planning is so much fun."
Williams' mother, Joanne, said they were excited to have Kopua in the family and already considered him their son-in-law.
"He is a very good man ... she is absolutely over the moon. He's a nice guy and she really looks well and feels well and is happy in herself," Joanne said.
She said the casual proposal was expected.
"I know they had been to the gym and I think they were just relaxing by the pool-side and he just popped up with the little box ... neither of them are really romantic."
Williams planned to get married in February or March next year and would most likely avoid the typical white wedding, Joanne said.
"I don't think it will be a white wedding; she will probably wear some other colour than white; that's just her."
Kopua's mother said she had been "sworn to secrecy" when approached by the Herald on Sunday, and Williams did not want to comment.
Meanwhile, Andrew Mulligan and Emma Phillips have been talking about their engagement on Twitter since Friday.
"Epic holiday. No work. Snowboarding. Shopping. Drinking. Oh yeah ... And got ENGAGED!!!," Phillips tweeted.