She claimed she was disappointed, however, at not winning the "Best Kiss" award for her Moulin Rouge clinch with Ewan McGregor. That award went to two male actors, Jason Biggs and Seann William Scott, for the comedy American Pie 2.
Will Smith, who was nominated for an Oscar this year, captured Best Male Performance for his role as Muhammad Ali in Ali, and Reese Witherspoon took the award for Best Comedic Performance for Legally Blonde.
Witherspoon's success in that role made her one of the most sought-after comedy actresses in Hollywood. Denzel Washington was named Best Villain for his role as a maverick cop in the thriller Training Day, for which he had also won this year's Best Actor Oscar.
His competition included Zhang Ziyi from Rush Hour 2, Christopher Lee from The Lord of the Rings, Tim Roth from Planet of the Apes and the late singer Aaliyah from Queen of the Damned.
Britney Spears missed out on the award for Breakthrough (Female) for her debut movie role in Crossroads. The award went to fellow popstar Mandy Moore for A Walk To Remember.
Other awards included Best Action Sequence, which went to Pearl Harbor, and Best Fight, which was won by Chris Tucker and Jackie Chan for Rush Hour 2.
* The MTV Movie Awards will be broadcast on TV3 on Friday June 14, 8.30pm.
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