"I do love Russell. I do really, really think the world of him," she said.
"He loves wildlife, he is very considerate about helping what we are doing and is a good guy."
The pair have remained close friends for years, following the death of Irwin's late husband Steve, in 2006.
Crowe was a good friend of Steve's, and has regularly spoken of his relationship with the family in the past.
"I was great friends with Steve and his wife and his kids are really important to me. They're beautiful people," he told Newscorp.
"Terri is one of the greatest women I've ever met in my life, without there being implication of intimacy or whatever.
"You know I do love Terri Irwin, I love her kids and I love how she's kept the memory of Steve alive, and respected the work that the two of them had begun and she's an absolute champion."