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With comical timing the Wolverhampton-born songwriter flicks between two faces - brief smile and unhappy resting face - as he grabs camera after camera off the hungry fans pushing against the barriers.
The clip, which has since gone viral, prompted fans to give their opinions on his selfie fail.
Niall Horan of One Direction. Photo / Getty Images
One fan commented: "This Vine of Liam Payne wishing he was dead while taking selfies with fans is my favourite thing in the world."
While another added: "Hahahaha this cracks us up! #LiamPayne is sooo over taking selfies!"
Louis Tomlinson of One Direction. Photo / Getty Images
However it seems like the songwriter has yet to see the funny side, taking to Twitter to defend himself on Thursday night.
"Lots of people saying I was 'faking' smiles with fans yesterday... I usually find when ur [sic] taking a photo u don't smile until somebody's about to take the photo
"Sorry to disappoint but I don't walk around like this all day," he wrote including an emoticon of a beaming face. "That would hurt!"
A legion of female fans had turned out to greet the famous five as they walked the red carpet ahead of the awards ceremony at The Star in the harbour city.
Harry Styles of One Direction. Photo / Getty Images
The Brit pop band picked up the gong for Best International Artist at the star studded event and despite Liam's less than enthused time red carpet greeting, the band made sure to thoroughly thank their fans.
"Thank you so much, this is an absolute honour, it's incredible to be here in Australia," Louis said as he gripped the ARIA.
One Direction on stage during the 28th Annual ARIA Awards in Australia. Photo / Getty Images
"This award is for our fans, coming from the UK it's great having this support in Australia, we can't wait to be back on tour and see you guys in February," Zayn concluded for the boys.
- Daily Mail