The 31-year-old reality star was promoting her new fragrance True Refection at The London Hotel in West Hollywood when an unidentified woman pelted her with white powder.
Dressed in a black blazer, leather trousers and an electric blue blouse, Kim's hair and entire back were covered by what firefighters later found to be cooking powder.
According to TMZ.com, security guards took her to a private room where she brushed herself down before choosing to return to the event.
Talking to E! News, the shocked star said: "That probably is the craziest, unexpected, weird thing that ever happened to me.
"Like I said to my makeup artist, I wanted more powder and that's a whole lot of translucent powder right there."