They announced their heartbreaking split after just two and a half years of marriage on Thursday.
And as Jennifer Aniston and Justin Theroux adjust to their separation, it was claimed the pair had taken a crucial step to protect their multi-million dollar fortunes, with an "iron-clad" pre-nup signed before their August 2015 wedding, reports US Weekly.
A source told the website: "Jennifer has an iron-clad prenup with Justin. It would be very hard for Justin to contest it. The prenup talks before the marriage were long and intense."
"Jen's assets and Friends fortune are protected."
Jennifer, 49, who is most famous for her portrayal of Rachel Green on iconic sitcom Friends, is worth an estimated $200m (NZD $270M) , reports Daily Mail.