Hathaway recalled the story while at director Tom Hooper's series of screenings of the hotly anticipated musical adaptation at Alice Tully Hall in New York City on Friday.
The actress also had to shave her long brunette hair for the role and joked she barely recognised herself after transforming for the film - claiming she looked more like her older brother Michael.
"When I eventually looked in the mirror I just thought I looked like my gay brother," she said at the screening.
Over the weekend, the cast also travelled to Los Angeles for multiple screenings of the movie - with Barbra Streisand spotted in attendance at one viewing.
Les Miserables also stars Kiwi actor Russell Crowe, Amanda Seyfried, Helena Bonham Carter and Sacha Baron Cohen.
- COVER MEDIA