Adele's theme for the new Bond film Skyfall has shot to the top of the iTunes chart within hours of its release.
The track is hotly tipped to become the first 007 theme to make it to No. 1 in the official UK chart when it is announced on Sunday.
Adele's song, which shares its title with the movie, was given its full premiere on her website and made available to download. Fans had been given a taster of the track earlier in the week when it was leaked online, then swiftly removed.
The song - for which she teamed with Paul Epworth once more, who co-wrote and produced her massive hit Rolling In The Deep - is her first new material since her career exploded following the success of second album 21 early last year.
Previous Bond theme artists have all failed to take their songs to the top of the charts, including Sir Paul McCartney, Sir Tom Jones and Madonna, while Duran Duran made it to just No. 2 in 1985 with A View to a Kill.