Whanganui firefighter Aaron Summerhays will fly to New South Wales to support the response to widespread flooding in the state.
More than 80 millimetres of rain fell between Sunday and Monday in several inland areas of the state, resulting in flash flooding.
NSW State Emergency Services took 462 calls for help over 24 hours, with people trapped by the sudden floodwaters.
Australian emergency services minister Steph Cooke said the state government asked New Zealand for assistance in the flood rescue efforts.
Fire and Emergency New Zealand (FENZ) national manager of response capability Paul Turner said a team of 12 people would arrive in Sydney on Tuesday to assist in a variety of support roles including operations, planning, public information, logistics, resources and air support.